Solar methanol and the third industrial revolution

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South Korean researchers develop new methanol fuel cell which, when coupled with solar energy, could prove revolutionary. God help Queensland coal.

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The Hydrogen Economy has often been touted as the next big energy source. However, due to the prohibitive cost of its infrastructure, hydrogen has gone out of favour. Fairly recently, Professor George Olah, Nobel Laureate, has proposed using methanol (think methylated spirits). Methanol is a liquid at room temperature, it can be used in the pre-existing gasoline infrastructure and, unlike LNG, it can be transported by ordinary oil tanker.

However, the tantalising promise of methanol is that it can be used as a fuel in a fuel cell. Fuel cells can operate at an efficiency of 80 per cent, as against gas-fired steam turbines of 50 per cent, and coal-fired steam turbines of 40 per cent. These are best practice numbers; many Chinese coal-fired steam turbines are much less efficient than 40 per cent.

Because the fuel cell stack can be located close to the consumer, the 20 per cent “cogenerated” waste heat can be ducted to the consumer (for space heating) along with the electricity, resulting in 100 per cent fuel efficiency.

The ideal fuel cell for methanol will consume the methanol directly and not need a (steam reformation) unit at its front end to preconvert the methanol into hydrogen and carbon dioxide.

Up to now, two fuel cell types seem to have emerged from the scrum, the solid polymer and the solid oxide. Both of these have crippling disadvantages.

Firstly, the solid polymer cell. The proton-exchange “nafion” polymer membrane fuel cell uses platinum. End of story! Also, platinum catalysts are prima donnas. They hate carbon dioxide. Even the tiniest amount of carbon dioxide that escapes the hydrogen scrubber will convert to carbon monoxide and “poison” the platinum. Methanol will “cross over” the electrolyte and combine with the oxygen directly, without forming an external circuit. This greatly reduces the output current.

Secondly, the Solid Oxide Cell (SOFC). The SOFC operates at 1000°C, continuously. It can use methanol, but it is so costly!

However … a couple of days ago, a South Korean research team at the Ulsan National Institute of Science and Technology has disclosed a cheap, iodine coated graphene-based direct methanol fuel cell. They have reported that this fuel cell generates 33% more current than platinum, is unaffected by carbon monoxide, and does not display “methanol cross-over”. If it can be commercialised, this fuel cell could be the holy grail that will usher in Olah’s “Methanol Economy.”

Traditionally, methanol has been produced by the steam reformation of natural gas. However, there is another pathway. If carbon dioxide and hydrogen are processed in the presence of a copper/zinc oxide/ alumina catalyst, the result is satisfactory levels of methanol and water.

Hydrogen can be produced by electrolysis, which, in turn, leads to the idea of solar-derived electricity. Methanol, produced in this fashion, is effectively liquid sunshine, to be used whenever and wherever required.

The fuel cell stack can be used as a “neighbourhood power station”, thereby dispensing with the steam turbine’s electricity network. The methanol could be delivered in “Grey Ghost” tankers. Carbon Capture technology separates the carbon dioxide from the water and the former is piped to a central pipeline pumping station, or to a liquification plant for loading aboard a tanker. The water could be collected and back loaded in the methanol tankers.

The cycle is completely renewable and makes methanol available for electricity generation at all hours of the day, to augment the output of rooftop solar sytems.

Addendum: The Tibetan plateau is the richest wind resource on the planet. If an effective regenerative braking system could be devised, the power required by the water going up could be offset by the power released by the methanol coming down.

Politically, this new Korean fuel cell means that Global Greenhouse is changing from an environmental issue into an economic and industry policy issue.

Economically, thermal coal is a carcass, swinging in the breeze, just waiting to be cut down. God help Queensland!

Conclusion: As with the First and Second Industrial Revolutions, lowest emissions are only the beginning!

Noel Clothier is a member of the Australian Greens in Queensland

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4 Comments
  1. SunWind Solar 6 years ago

    …might be a little energy-expensive compressing the C02, and tanking it back to where you started from…but rather playful – a good post. Only in cycles is any of this “sustainable”, and the sooner we grasp spin, the better…

  2. Bob_Wallace 6 years ago

    Nit-picking. Almost 100%. Not a lot of need for space heating in the summer.

    But the larger issue. Where does the concentrated CO2 needed for methanol come from? Coal smoke stacks?

    • andrew 4 years ago

      You can buy CO2 in bottles for MIG welding already. Where it comes from is matter of choice.

  3. andrew 4 years ago

    Methanol can be created by mixing LNG and CO2. Many homes across the world already have LNG into their homes for heater, oven, hot water

    That would mean, in conjunction with say a Tesla Powerwall a home, expecially an isolated one, or isolated town have the capacity to generate and store electricity.

    CO2 is sold in gas bottles in a number of forms

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